Adobe Color Themes
When looking for a color scheme, make your life easier by using Adobe Color Themes (formally known as Kuler).
In Photoshop CC go to Window > Extensions > Adobe Color Themes to open up the Color Themes Panel which will let you create color schemes or choose from thousands of user contributed schemes.
If you have CS6 or below, you can still use the Adobe Color Themes web app. simply go to color.adobe.com.